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乙烯基单体/N-取代马来酰亚胺共聚合动力学
引用本文:单国荣,翁志学,黄志明,潘祖仁.乙烯基单体/N-取代马来酰亚胺共聚合动力学[J].高等学校化学学报,1999,20(4):651-655.
作者姓名:单国荣  翁志学  黄志明  潘祖仁
作者单位:浙江大学化工系、高分子科学与工程研究所, 杭州 310027
基金项目:教育部博士学科点专项科研基金
摘    要:详细研究了聚合温度、引发剂用量、单体配比对苯乙烯(St)/N-苯基马来酰亚胺(PMI)共聚合动力学的影响.对St、甲基丙烯酸甲酯(MMA)和丙烯腈(AN)等单一或混合单体与PMI、N-环己基马来酰亚胺(ChMI)和N-邻氯苯基马来酰亚胺(o-CPMI)的共聚合进行了研究,并讨论了单体结构的影响.

关 键 词:乙烯基单体  N-取代马来酰亚胺  共聚合动力学  
收稿时间:1998-08-24
修稿时间:: 1998-08-24.

Kinetics of Vinyl Monomer/N-Substituted Maleimide Copolymerization
SHAN Guo-Rong,WENG Zhi-Xue,HUANG Zhi-Ming,PAN Zu-Ren.Kinetics of Vinyl Monomer/N-Substituted Maleimide Copolymerization[J].Chemical Research In Chinese Universities,1999,20(4):651-655.
Authors:SHAN Guo-Rong  WENG Zhi-Xue  HUANG Zhi-Ming  PAN Zu-Ren
Institution:Department of Chemical Engineering, Institute of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027
Abstract:The effects of reaction temperature, initiator concentration, and molar fraction of monomer on the copolymerization kinetics of styrene/Nphenylmaleimide were studied in detail. The copolymerizations of styrene, methyl methacrylate, acrylonitrile, or their mixtures with \{Nphenylmaleimide\}, Ncyclohexylmaleimide, or N(ochlorophenyl)maleimide were also investigated and discussed with the structure of comonomer pairs.
Keywords:Vinyl monomer  NSubstituted maleimide  Kinetics of copolymerization  
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