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S-(1-二茂铁烷基)硫代乙醇酸与胺的反应——一类新型二茂铁衍生物的合成与性质研究
引用本文:王冀英,向进福. S-(1-二茂铁烷基)硫代乙醇酸与胺的反应——一类新型二茂铁衍生物的合成与性质研究[J]. 无机化学学报, 1989, 0(2)
作者姓名:王冀英  向进福
作者单位:陕西师范大学化学系 西安(王冀英),陕西师范大学化学系 西安(向进福)
摘    要:Ratajczak等研究了S-(1-二茂铁烷基)疏代乙醇酸的合成与反应(?)Ugi等将它们与羟胺反应,合成了一种有用的手性模板试剂。最近,Czech等用键合载体液相色谱对它们进行了光学拆分研究。本文报导了此类化合物与胺的反应,合成了一类新的化合物(?)二茂铁烷基)硫代乙醇酸胺。

关 键 词:二茂铁  硫代乙醇酸    反应  胺盐

REACTIONS OF S-(1-FERROCENYLALKYL) THIO-GLYCOLIC ACIDS WITH AMINES-STUDIES ON SYNTHESES AND PROPERTIES OF A NOVEL TYPE OF FERROCENYL DERIVATIVES
Wang Jiying Xiang Jinfu. REACTIONS OF S-(1-FERROCENYLALKYL) THIO-GLYCOLIC ACIDS WITH AMINES-STUDIES ON SYNTHESES AND PROPERTIES OF A NOVEL TYPE OF FERROCENYL DERIVATIVES[J]. Chinese Journal of Inorganic Chemistry, 1989, 0(2)
Authors:Wang Jiying Xiang Jinfu
Abstract:This article reported reactions of S-(1-ferrocenylalkyl)thioglycolic acids and amines. Some novel type of ferrocenyl derivatives-alkyl ammonium S-(1-ferrocenylalkyl) thioglycolic were synthesized and characterized by elemental analyses.IR and H NMR spectroscopy. Their molar conductance ratios were measured, and some influences of kinds of amines were discussed.
Keywords:ferrocene thioglycolic acid amine reaction ammonlnm salt
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