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Circular dichroism—LI : Circular dichroism of derivatives of hop constituents containing a five-membered ring
Authors:D De Keukeleire  G Snatzke
Institution:1. Organic Chemistry Department, State University of Ghent, Krijgslaan, 271, Building S.4, B-9000 Ghent Germany;2. Organisch-chemisches Institut der Universität Bonn, Meckenheimerallee 168, D-53 Bonn Germany
Abstract:The conformation of the cyclopentenones 5 to 8 is determined from their CD-spectra. The site of enolization and the conformation of cis- and trans-isohumulone (1 and 2) is determined with the help of the CD-spectra, the direction of enolization for the humulinic acids 3 and 4 is tentatively determined by the same method.
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