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The free energy,enthalpy and entropy changes of the dissociation of diprotonated diamines
Authors:H.S. CreyfL.C. Van Poucke
Affiliation:Department of General and Inorganic Chemistry, University of Ghent, Ghent Belgium
Abstract:The ΔG, ΔH and ΔS values of the dissociation of a number of diprotonated diamines were determinated by potentiometric and calorimetric methods, in 1M KNO3, at 25°C. The results are discussed in terms of solvent effects, the theory of Kirkwood and Westheimer, and microscopic constants.
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