An infrared study of the tautomerism of chlorinated 2-pyridinols isolated in an argon matrix |
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Authors: | Stanley ST King Wendell L DillingNancy B Tefertiller |
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Institution: | Chemical Physics Research and E. C. Britton Research, Dow Interdiscipline Group, The Dow Chemical Company, Midland, Michigan 48640 USA |
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Abstract: | The infrared spectra of 3-, 4-, 5- and 6-monochloro-, 3,5,6-trichloro-2-pyridinols (pyridones), and of the unsubstituted 2-pyridinol isolated in a low temperature (20°K) argon matrix were studied. The results indicate that the enol/keto ratio for the isolated pyridinols decreases according to the position of the chlorine atom(s) on the pyridine ring; i.e., 3,5,6-trichloro >-6 > 5 > 4 > 3 monochloro-2-pyridinols. 3,5,6-Trichloro-2-pyridinol exists predominantly in the enol form. |
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