Notable norbornene (NBE) incorporation in ethylene-NBE copolymerization catalysed by nonbridged half-titanocenes: better correlation between NBE incorporation and coordination energy |
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| Authors: | Nomura Kotohiro Wang Wei Fujiki Michiya Liu Jingyu |
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| Institution: | Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama, Ikoma, Nara 630-0101, Japan. nomurak@ms.naist.jp |
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| Abstract: | CpTiCl2(N=CtBu2) exhibits both remarkable catalytic activity and efficient norbornene (NBE) incorporation for ethylene-NBE copolymerization: the NBE incorporation by Cp'TiCl2(X) (X = N=CtBu2, O-2,6-iPr2C6H3; Cp' = Cp, C5Me5, indenyl) was related to the calculated coordination energy after ethylene insertion. |
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