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Study on the pyrolysis of Moroccan oil shale with poly (ethylene terephthalate)
Authors:A. Aboulkas  K. El Harfi  A. El Bouadili  M. Nadifiyine
Affiliation:1.Laboratoire de Recherche sur la Réactivités des Matériaux et l’Optimisation des Procédés??REMATOP?, Département de chimie, Faculté des Sciences Semlalia,Université Cadi Ayyad,Marrakech,Morocco;2.Laboratoire Interdisciplinaire de Recherche en Sciences et Techniques, Faculté polydisciplinaire de Béni-Mellal,Université Sultan Moulay Slimane,Beni-Mellal,Morocco
Abstract:Investigations into the pyrolytic behaviours of oil shale, poly (ethylene terephthalate) (PET) and their mixture have been conducted using a thermogravimetric analyzer. Experiments were carried out dynamically by increasing the temperature from 298 to 1,273 K with heating rates of 2–100 K/min under a nitrogen atmosphere. Discrepancies between the experimental and calculated TG/DTG profiles were considered as a measurement of the extent of interactions occurring on co-pyrolysis. The maximum degradation temperature of each component in the mixture was higher than those the individual components; thus an increase in thermal stability was expected. The kinetic processing of thermogravimetric data was carried out using Flynn–Wall–Ozawa (FWO) method.
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