Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements via proton-induced reversible metal migration |
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| Authors: | Dubs Christian Inagaki Akiko Akita Munetaka |
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| Affiliation: | Chemical Resources Laboratory, Tokyo Institute of Technology, R1-27, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan. |
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| Abstract: | Pairs of isomeric heterodinuclear complexes, [(cod)Ir(mu-PNNN)M(L)]BF4 and [(L)M(mu-PNNN)Ir(cod)]BF4, with switched metal arrangements are prepared in a specific manner by simply changing the addition order of the reagents. |
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