Synthesis of Heterocycles Based on Products of Anion Arylation of Unsaturated Compounds. 5. Reaction of 2-Aryl-1,4-benzoquinones with Thiourea |
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Authors: | N D Obushak V S Matiichuk and R L Martyak |
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Institution: | (1) Lvov Ivan Franko State University, Lvov, 290602, Ukraine |
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Abstract: | 2-Aryl-1,4-benzoquinones, that can be obtained by arylation of quinone by arenediazonium salts, regioselectively react with thiourea in acid medium to form 7-aryl-5-hydroxy-1,3-benzoxathiol-2-ones. In the presence of excess arylquinones at room temperature, 2-amino-6-hydroxybenzothiazoles are formed in the same reaction. |
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Keywords: | 2-aryl-1 4-benzoquinones thiourea |
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