Stereochimie de la reaction de rupture par le brome de la liaision siliciumaryle du dimethyl-1,2 phenyl-1 silacyclopentane |
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| Authors: | Jacques Dubac Pierre Mazerolles Monique Joly |
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| Institution: | Laboratoire des Organométalliques, Université P. Sabatier, 118 route de Narbonne, 31077-Toulouse-Cedex France |
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| Abstract: | Stereospecific synthesis of geometric isomers of 1,2-dimethyl-1-phenylsilacyclopentane is described. We demonstrate that brominolysis of the arylsilicon bond occurs with predominant inversion of configuration at the silicon atom of the silacyclopentane ring. |
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