Bis-aryldiazo complexes of manganese |
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| Authors: | Barry L. Haymore |
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| Affiliation: | Department of Chemistry, Indiana University, Bloomington, Indiana 47401 U.S.A. |
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| Abstract: | The first bis-aryldiazo complexes containing manganese of the type MnX(N2Ph)2(PPh3)2 and Mn(CO)(N2Ph)2(PPh3)2+PF6? have been prepared from Mn(CO)2(N2Ph)(PPh3)2 (X Cl, Br, NCO). In addition, the mixed aryldiazonitrosyl analogues and the dinitrosyl analogues have been prepared in order to compare their spectroscopic properties with the bis-aryldiazo complexes. The preparation of the rhenium complex Re(CO)2(N2Ph)(PPh3)2 is also reported. |
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