Reactions of (η5-C5H5)Fe(CO)2(η1-C5H5) with phosphorus donor ligands |
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| Authors: | Jay A Labinger |
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| Institution: | Department of Chemistry, University of Notre Dame, Notre Dame, Indiana 46556 USA |
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| Abstract: | The course of the reaction of (η5-C5H5)Fe(CO)2(η1-C5H5) with phosphorus donor ligands depends strongly on the nature of the ligand; products derived from an Arbuzov-like rearrangement or from reduction have been found as well as the expected simple substitution product. The dynamic PMR behavior of (η5-C5H5)Fe(CO) (P(OPh)3) (η1-C5H5) has been examined. |
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