Vinylidene complexes of transition metals : III. Derivatives of cyclopentadienyltricarbonyl rhenium with phenylvinylidene ligands. Crystal and molecular structure of Cp(CO)2Re[CC(Ph)C(Ph)CH2]Re(CO)2Cp期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Vinylidene complexes of transition metals : III. Derivatives of cyclopentadienyltricarbonyl rhenium with phenylvinylidene ligands. Crystal and molecular structure of Cp(CO)2Re[CC(Ph)C(Ph)CH2]Re(CO)2Cp

Authors:	N.E. Kolobova A.B. Antonova O.M. Khitrova M.Yu. Antipin Yu.T. Struchkov

Affiliation:	Institute of Organo-Element Compounds, Academy of Sciences of the U.S.S.R., Vavilov Str. 28, Moscow, B-312 U.S.S.R.

Abstract:	The novel complexes CpRe(CCHPh)(CO)₂ and Cp₂Re₂(μ-CCHPh)(CO)₄ containing a terminal and a bridging phenylvinylidene ligand respectively and the binuclear complex Cp(CO)₂Re[CC(Ph)C(Ph)CH₂]Re(CO)₂Cp were obtained in the reaction of CpRe(CO)₃ with PhCCH.According to an X-ray study of the latter complex the unusual bridging ligand is η¹-bonded to one Re atom and η²-bonded to the other.

Keywords:	Address correspondence to these authors.
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