The thiolate anion as a nucleophile Part VII. Reactions of some fluorinated anilines and phenylhydrazines |
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Authors: | W.James Frazee Michael E. Peach James R. Sweet |
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Affiliation: | Chemistry Department, Acadia University, Wolfville, Nova Scotia, B0P 1X0 Canada |
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Abstract: | Direct nucleophilic substitution with sodium methanethiolate of the fluorinated anilines and phenylhydrazines, pentafluorophenylaniline, the three isomeric tetrafluoroanilines, pentafluorophenylhydrazine, and 2,3,5,6-tetrafluorophenylhydrazine, gave replacement of one or two fluorine atoms. The new compounds isolated have been characterized by elemental analysis, infrared and mass spectra and their stereochemistries have been deduced from their NMR spectra (1H, 19F and, in one instance, 13C). |
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