The reaction of o-nitro- and p-nitro-phenyl selenocyanates with arylthiols |
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| Authors: | ER Clark MAS Al-Turaihi |
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| Institution: | Department of Chemistry, University of Aston in Birmingham, Gosta Green, Birmingham B4 7ET Great Britain |
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| Abstract: | The interaction of o-nitro- and p-nitro-phenyl selenocyanate with aromatic thiols p-thiocresol, p-chlorothiophenol, 4-bromothiophenol, o-mercaptobenzoic acid and pentafluorothiophenol in non-aqueous media and under an atmosphere of dry nitrogen has been investigated. The main products are the diselenide or the selenenyl sulphide depending on the reactants. Hydrogen cyanide is given in all cases. The IR and Raman spectra of the diselenides and selenenyl sulphides are considered. |
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| Keywords: | To whom correspondence should be addressed |
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