Syntheses of organometallic compounds containing iminoacyl ligands. Reactions of metal carbonyl anions with imidoyl halides |
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| Authors: | Richard D. Adams Daniel F. Chodosh Nancy M. Golembeski |
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| Affiliation: | Department of Chemistry, Yale University, New Haven CT 06520 U.S.A. |
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| Abstract: | Reactions of metal carbonyl anions with imidoyl halides provide a convenient route for the preparation of organometallic complexes containing both η1- and η2-iminoacyl ligands. With poorer nucleophiles such as tetracarbonyl cobaltate anion, coupling of imidoyl groupings becomes important. This is illustrated by the molecules Co2(CO)5(P(CH3)2C6H5){(C6H5)CN(C6H5)}2 which has been crystallographically analyzed. |
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