Syntheses of fluorine-containing fused polycyclic compounds: photo-cycloaddition of indene to cyclic fluoro-olefins and some reactions concerning the adducts |
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| Authors: | Hiroshi Kimoto Hiroshige Muramatsu Kan Inukai |
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| Institution: | Government Industrial Research Institute, Nagoya ; Hirate-machi, Kita-ku, Nagoya 462 Japan |
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| Abstract: | Acetophenone photo-sensitized addition of indene to cyclic fluoro-olefins (1,2-dichlorohexafluorocyclopentene-1, 1,2-dichlorotetrafluorocyclobutene-1 and hexafluorocyclobutene) gave the corresponding cycloadducts in satisfactory yields. The cycloadducts obtained predominantly had exo configuration.Some reactions such as reduction, oxidation, dechlorination and halogenation, of the cycloadducts were also studied. |
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