The lack of intramolecular carbonyl ligand rearrangement in the stereospecifically 13co labelled (diamine)molybdenum tetracarbonyl derivatives |
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| Authors: | D.J. Darensbourg L.J. Todd J.P. Hickey |
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| Affiliation: | Department of Chemistry, Tulane University, New Orleans, Louisiana 70118 U.S.A.;Department of Chemistry, Indiana University, Bloomington, Indiana 47401 U.S.A. |
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| Abstract: | The preparation and spectral characterization of stereospecifically, axially labelled Mo(CO)3(13CO)(diamine) complexes (diamine N,N,N′,N′-tetramethylethylenediamine and N,N,N′,N′-tetramethyl-1,3-diaminopropane) and the rigidity (or lack of fluxionality) of the carbonyl ligands during subsequent thermal reactions of these derivatives are reported. |
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