Electrochemical fluorination of chlorine-containing amines |
| |
Authors: | Kota Omori Shunji Nagase Hajime Baba Kazuo Kodaira Takashi Abe |
| |
Institution: | Government Industrial Research Institute, Nagoya, Hirate-machi, Kita-ku, Nagoya 462 Japan |
| |
Abstract: | The electrochemical fluorination of chlorine-containing alkylamines has been studied. It was found that, in general, the carbon-chlorine bond in the alkylamines is retained during electrochemical fluorination is anhydrous hydrogen fluoride, yielding chlorine-containing polyfluoroalkylamines. Perfluoroalkylamines and fluorocarbons were also produced.By the use of this method, several new chloropolyfluoroamines such as (CF3)2NCF2CClF2, (C2F5)2NCF2CClF2, (CF3)(C2F5)NCF2CClF2, (CClF2CF2)2NCF3, (CClF2CF2)2NC2F5, (C2F5)(CClF2CF2)NF, (CClF2CF2)2NF, (CF3)2NCF2CF2CClF2, CF2CClF2, and CF2CClF2 have been isolated and characterized. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|