Exchange effects on the 1H and 31P nmr spectra of cyclodiphosph(III)azane selenides and tellurides |
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Authors: | R Keat DG Thompson |
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Institution: | Department of Chemistry, University of Glasgow, Glasgow, G12 8QQ Great Britain |
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Abstract: | Oxidation of the isomeric cyclodiphosph(III)azanes, (Me2 NPNBu-t)2, by selenium and by tellurium gives both isomeric monoselenides but only one monotelluride. Variable temperature 1H and 31P NMR studies provide evidence for restricted rotation about the exocyclic PN bonds, and in the telluride, of exchange of tellurium between the phosphorus atoms. |
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