Hydroformylation of deuterated olefins in the presence of cobalt catalysts : II. Experiments at low pressure of carbon monoxide |
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| Authors: | Mario Bianchi Franco Piacenti Piero Frediani Ugo Matteoli |
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| Affiliation: | Istituto di Chimica Organica, Università di Firenze, Via Gino Capponi 9, 50121 Florence Italy;Centro di Studio sulle Cause di Deperimetno e Metodi di Conservazione delle Opere d''Arte del C.N.R., Via Gino Capponi 9, 50121 Florence Italy |
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| Abstract: | Complete retention of deuterium is observed during the hydroformylation of deuterated olefins even with a low partial pressure of carbon monoxide. Inter- and intra-molecular redistribution of deuterium does take place, however. An olefin—catalyst complex containing two molecules of olefin is suggested to rationalize the results. |
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| Keywords: | To whom inquiries should be directed. |
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