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Asymmetric hydrogenation using ferrocenylphosphine rhodium(I) cationic complexes |
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| Authors: | William R Cullen E-Shan Yeh |
| Institution: | Department of Chemistry, University of British Columbia, Vancouver, V6T 1W5 Canada |
| Abstract: | High optical yields are obtained in the hydrogenation of α-acetamidocinnamic acid using (COD)Rh((+)PPFA)]ClO4 and related complexes as catalysts. (+)PPFA is (S)-α-(R)-2-diphenylphosphinoferrocenyl] ethyldimethylamine. |
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