Aromatic substitution of olefins. Arylation with anilines via the C-N bond cleavage in the presence of palladium(II) acetate |
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| Authors: | Fumitaka Akiyama Shiichiro Teranishi Yuzo Fujiwara Hiroshi Taniguchi |
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| Institution: | Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka 560, Japan;Department of Applied Chemistry, Faculty of Engineering, Kyushu University, Hakozaki, Fukuoka 812, Japan |
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| Abstract: | A new aromatic substitution reaction of styrene by arylamines such as aniline, (unp)-toluidine, (unp)-anisidine, (unp)-chloroaniline, and (unp)-nitroaniline in the presence of palladium(II) acetate has been found to give (E)-stilbene, (E)-(unp)-methylstilbene, (E)-(unp)-methoxystilbene, (E)-(unp)-chlorostilbene, and (E)-(unp)-nitrostilbene, respectively, in modest yields. |
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| Keywords: | To whom correspondence be addressed at Boston University |
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