The adsorption of quaternary ammonium salts at a mercury solution interface: Part II. Non-symmetrical quaternary ammonium salts |
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| Authors: | E. Bou Karam R. Bennes D. Bellostas |
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| Affiliation: | Groupe de Recherche de Physico Chimie des Interfaces, C.N.R.S., B.P. 5051, 34033 Montpellier Cédex (France) |
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| Abstract: | The adsorption of triethyl alkyl (and allyl) ammonium bromides on a mercury electrode has been investigated. The isotherms and values of the free energy of adsorption yield information on the mode of adsorption of the cations. The formation of partial bimolecular films on the surface of mercury by the cations studied has been described and a simple explanation put forward concerning the mechanism of destruction of these films. |
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| Keywords: | To whom communication should be addressed. |
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