An unusual oxidative addition-ligand elimination reaction. Preparation and structure of RhCl2(PMe2Ph)2(C3Ph3) |
| |
| Authors: | P Douglas Frisch GP Khare |
| |
| Institution: | Department of Chemistry, University of Maine, Orono 04473 U.S.A. |
| |
| Abstract: | The sym-triphenylcyclopropenium cation (C3Ph3+) stabilized as the Cl? or PF6? salt, undergoes facile reactions at room temperature with trans-Rh(CO)Cl(PMe2Ph)2 to produce complexes which result from the oxidative cleavage of the ring and decarbonylation of the organometallic reactant. The product of the C3Ph3+Cl? reaction has been fully characterized by X-ray analysis and is shown to be RhCl2(PMe2Ph)2(C3Ph3). |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
