The 1H NMR spectra of methylmethoxyaluminium chloride and methylmethoxyaluminium iodide |
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Authors: | A. Kunicki W. Kosińska M. BolesŁawski S. Pasynkiewicz |
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Affiliation: | Institute of Organic Chemistry and Technology. Technical University (Politechnika), ul. Koszykowa 75, 00-662 Warszawa Poland |
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Abstract: | It has been shown by means of 1H NMR, IR and cryometrical measurements that, with oxygen bridges, Me(OMe)AlCl and Me(OMe)AII are trimers in solutions.Two isomers, cis and trans, are present, which are responsible for the multiple 1H NMR spectra. The proton signals of MeAl and OMe groups are assigned in each isomer. |
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