Reactions of iron carbonyl complexes with dimethylthiocarbamoyl chloride |
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| Authors: | W.K. Dean |
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| Affiliation: | Department of Chemistry, Emory Univresity, Atlanta, Georgia 30322 U.S.A. |
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| Abstract: | The reactions of dimethylthiocarbamoyl chloride with a number of neutral and ionic iron carbonyl complexes in tetrahydrofuran are described. A variety of unusual products were obtained, viz. Fe(CO)2(S2CNMe2)2 from Fe(CO)5; Fe(CO)2(S2CNMe2)(CSNMe2) from Fe2)CO)9, Fe3(CO)12, and Fe(CO)42?; [Fe-(CO)2(S2CNMe2)(CNMe2)(CNMe2)2S]+ from Fe(CO)42?, and Fe4(CO)12S(CSNMe2)-(CNMe2) from Fe2(CO)82?, as well as Fe2(CO)6(CSSEt)2 from Fe2(CO)9 and ClCSSEt. The structures and behavior and some reactions of these complexes are described. |
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