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Exchange and addition reactions involving tin—allyl compounds
Authors:Michael F. Fishwick  Malcolm G.H. Wallbridge
Affiliation:Department of Molecular Sciences, University of Warwick, Coventry CV4 7AL Great Britain
Abstract:Allyltin chlorides (or bromides) may be prepared by simple exchange reactions between tetraallyltin and the corresponding tetrahalide. Hydroboration of allylttrimethyltin yields the air-reactive borane, [Me3Sn(CH2)3]3B, which is readingly oxidised to the corresponding alcohol Me3Sn(CH2)3OH.
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