Exchange and addition reactions involving tin—allyl compounds |
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Authors: | Michael F. Fishwick Malcolm G.H. Wallbridge |
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Affiliation: | Department of Molecular Sciences, University of Warwick, Coventry CV4 7AL Great Britain |
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Abstract: | Allyltin chlorides (or bromides) may be prepared by simple exchange reactions between tetraallyltin and the corresponding tetrahalide. Hydroboration of allylttrimethyltin yields the air-reactive borane, [Me3Sn(CH2)3]3B, which is readingly oxidised to the corresponding alcohol Me3Sn(CH2)3OH. |
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