Photoinduced Elimination of H2 from [Mo(η5-C5H5)2H2]. Generation of Molybdenocene. |
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| Authors: | GL Geoffroy MG Bradley |
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| Institution: | Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802 USA |
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| Abstract: | Ultraviolet irradiation of deaerated solutions of Mo(η5-C5H5)2H2] results in elimination of H2 and generation of Mo(η5-C5H5)2]. The transient molybdenocene can be trapped with substrates such as CO, C2H2, and PR3 to yield stable adducts, but in the absence of substrate, oligomerization to the previously described Mo(η5-C5H5)2]x occurs. |
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| Keywords: | Author to whom correspondence should be sent |
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