Copolymer Microstructure by High-Resolution NMR Studies |
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Authors: | Koichi Ito Seigo Iwase Kazuo Umehara Yuya Yamashita |
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Institution: | DEPARTMENT OF SYNTHETIC , CHEMISTRY FACULTY OF ENGINEERING NAGOYA UNIVERSITY FURO-CHO , CHIKUSA-KU, NAGOYA, JAPAN |
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Abstract: | The monomer and configurational sequences of several radical copolymers between substituted styrenes and acrylates have been examined by analyzing the high-resolution NMR spectra with the previously reported treatment of the styrene-methyl methacrylate system. The analyses have led to the conclusion that the monomer sequence distribution is just as expected from the usual copolymerization theory with r 1 and r 2. |
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