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Optimal TBHP allylic oxidation of Delta5-steroids catalyzed by dirhodium caprolactamate |
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| Authors: | Choi Hojae Doyle Michael P |
| Affiliation: | Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA. |
| Abstract: | Dirhodium caprolactamate is the most efficient catalyst for the oxidation of Delta5-steroids to 7-keto-Delta5-steroids by 70% tert-butyl hydroperoxide in water (T-HYDRO). Isolated product yields range from 38 to 87%. |
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