Ti-Mo heterobimetallic thiacalix[4]arene complex containing an unusual alpha-agostic micro2-eta5:eta2-cyclopentadienyl ligand |
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| Authors: | Takemoto Shin Tanaka Shinpei Mizobe Yasushi Hidai Masanobu |
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| Institution: | Department of Materials Science and Technology, Faculty of Industrial Science and Technology, Tokyo University of Science, Noda, Chiba 278-8510, Japan. |
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| Abstract: | A stepwise reaction of p-tert-butylthiacalix4]arene (TC4A-(OH)(4)) with CpTiCl3]-NEt(3) and cis-Mo(N(2))(2)(PMe(2)Ph)(4)] afforded a new Ti-Mo heterobimetallic complex TC4A-(O)(4)Ti(micro2-C(5)H(5))MoH(PMe(2)Ph)(2)] which shows an unusual alpha-agostic micro2-eta5:eta2-coordination of a cyclopentadienyl ligand. |
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