Stable pi-dimer of a tetrathiafulvalene cation radical encapsulated in the cavity of cucurbit[8]uril |
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Authors: | Ziganshina Albina Y Ko Young Ho Jeon Woo Sung Kim Kimoon |
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Institution: | National Creative Research Initiative Center for Smart Supramolecules and Department of Chemistry, Division of Molecular and Life Sciences, Pohang University of Science and Technology, San 31 Hyojadong, Pohang 790-784, Republic of Korea. |
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Abstract: | The first stable pi-dimer of a tetrathiafulvalene (TTF) cation radical encapsulated in the cavity of cucurbit8]uril has been isolated at room temperature and fully characterized; it shows absorption bands at 400, 540 and 760 nm, characteristic of the TTF cation radical dimer. |
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