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Kinetics of competitive addition of methyldichlorosilane to 1-hexene and to acetone |
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| Authors: | Yu. M. Lugovoi A. G. Shostenko N. P. Tarasova I. A. Zaboluev K. E. Danilov C. Filliatre G. Bourgeois |
| Affiliation: | (1) D.I. Mendeleev Institute of Chemical Technology, Moscow, USSR;(2) Institute of Pine, Bordeaux, France |
| Abstract: | The competitive addition of methyldichlorosilane (MDChS) to 1-hexene and acetone** has been studied. The estimated relative constant is effective and depends on acetone concentration and does not obey the Arrhenius temperature equation. A possible explanation is the complexation of methlydichlorosilyl radicals by acetone molecules.
Initiated by  -irradiation of60Co. |
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