| 胶束电动毛细管色谱法分析手性化合物 |
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| 引用本文： | 何友昭,郑明珠,淦五二.胶束电动毛细管色谱法分析手性化合物[J].色谱,1999,17(1):26-29. |
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| 作者姓名： | 何友昭 郑明珠 淦五二 |
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| 作者单位： | 中国科学技术大学化学系 |
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| 摘 要： | 对近年来胶束电动毛细管色谱法（ＭＥＣＣ）分析手性化合物方面的工作进行了评述，简述了ＭＥＣＣ分离手性化合物的原理，并探讨了几种ＭＥＣＣ手性分离体系的分离机理。
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| 关 键 词： | 表面活性剂 胶束电动毛细管色谱法 手性分离 |
Analysis of Chiral Compounds by Micelle Electrokinetic Capillary Chromatography |
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| Y He,M Zheng,W Gan.Analysis of Chiral Compounds by Micelle Electrokinetic Capillary Chromatography[J].Chinese Journal of Chromatography,1999,17(1):26-29. |
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| Authors: | Y He M Zheng W Gan |
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| Institution: | University of Science and Technology of China, Hefei, 230026. |
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| Abstract: | An overview on applications of micelle electrokinetic capillary chromatography(MECC) in chiral compounds analysis is presented. Ionic chiral surfactants such as bile salts, long alkyl chain surfactants and high molecular weight surfactants, which can migrate with electroosmosis and its electrophoretic mobility, and interact with the solutes, are employed as chiral selectors. Addition of electrically neutral chiral selectors such as cyclodextrins is also successful in MECC separation. Theory of MECC enantiomer separation is briefly described. |
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| Keywords: | micelle electrokinetic capillary chromatography chiral separation surfactant |
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