| One novel multidimensional organic-inorganic hybrid based on polyoxometalates and copper chlorine coordination polymers with 4,4’-bipyridine ligands |
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| 作者姓名： | Li Chun Xuan Qing Jiang Pan |
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| 作者单位： | School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China |
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| 基金项目： | supported by the Key Project of Chinese Ministry of Education(No.211048);Program for New Century Excellent Talents in Heilongjiang Provincial University of China(No.1154-NCET-010) |
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| 摘 要： | One novel organic-inorganic hybrid materials with 4,4’-bipy ligands and copper chlorine coordination polymers as linkers,with new topology,{[CuI（4,4’-bipy）]10Cl2(SiW12O40)2}·6H2O（1）（4,4’-bipy = 4,4’-bipyridine）,has been hydrothermally synthesized. The single crystal X-ray structural analysis reveals that the structure of 1 is constructed from classical Keggin anions and[CuI（4,4’- bipy）]cations into a novel,three-dimensional（3D） polyoxometalates（POMs）based network.From the topological view,compound 1 is a novel（3.44.52.63）（32.44.56.69） topology.The electrochemical and photocatalysis properties of 1 have been investigated in details.
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| 关 键 词： | Polyoxometalate Tungstoferrate Framework Novel topology |
| 收稿时间： | 2012-01-19 |
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