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Phase diagram and isotope effect in cobaltites with spin-state transitions
Authors:N A Babushkina  A N Taldenkov  A V Kalinov  L M Fisher  O Yu Gorbenko  J Rohrkamp  T Lorenz  D I Khomskii and K I Kugel
Institution:1.Russian Research Center Kurchatov Institute,Moscow,Russia;2.All-Russian Electrical Engineering Institute,Moscow,Russia;3.Moscow State University,Moscow,Russia;4.II. Physikalisches Institut,Universit?t zu K?ln,K?ln,Germany;5.Institute for Theoretical and Applied Electrodynamics,Russian Academy of Sciences,Moscow,Russia
Abstract:The oxygen isotope effect was investigated in cobalt oxides (Pr1 − y Eu y )0.7Ca0.3CoO3 (0.12 < y < 0.26). The measurements of magnetization, electric resistivity, differential magnetic susceptibility, thermal expansion, and specific heat show that as the Eu concentration increases, a transition from “ferromagnetic metal” to “weakly magnetic insulator” is observed at y ≈ 0.18. In the insulating ground state, the transition occurs with a Co spin-state change that is suppressed in the ferromagnetic (FM) metallic phase. The spin-state transition at y > 0.18 is accompanied by a substantial oxygen isotope effect that is virtually absent in the FM phase (y < 0.18).
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