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Synthesis and photoluminescent properties of silica-coated LaCeF3:Tb nanocrystals
Authors:Ling Zhu  Jian Meng  Xueqiang Cao
Affiliation:(1) Key Lab of Rare Earth Chemistry & Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, Jilin, China;(2) Graduate School of The Chinese Academy of Sciences, Beijing, 100049, China
Abstract:La0.45Ce0.45F3:Tb (10 mol% Tb) nanoparticles was synthesized via sonochemical method and then coated with silica (SiO2) shells through a microemulsion process, resulting in the formation of core/shell structured LaCeF3:Tb/SiO2 nanoparticles. The obtained core/shell LaCeF3:Tb/SiO2 nanoparticles are spherical and uniform in size (average size about 60 nm), strongly fluorescent, and long fluorescence lifetime (1.87 ms). This kind of nanoparticles was water-soluble, which could be applied in biological labeling and other fields.
Keywords:Microemulsion  Lanthanide Fluorides  Silica  Core/Shell  Photoluminescent
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