| Abstract: | In the presence of Et4NCl·H2O, reaction of AgCl with TabHPF6 in MeCN afforded the title complex {(Tab-Tab)Ag2(μ-Cl)4]·2MeCN}n 1. 1 crystallizes in the orthorhombic space group Pbcn with a = 16.782(3), b = 6.8358(14), c = 26.194(5) A, V = 3004.9(10) A3, Z = 8,μ= 1.817 mm-1, Dc = 1.711 g/cm3, T= 223 K, C11H16AgCl2N2S, Mr = 387.10, F(000) = 1544, S = 1.160, R = 0.0528 and wR = 0.0896 for 2732 observed reflections with I > 2σ(I). 1 contains a 1D linear Ag2Cl4]n2n- chain coupled with the Tab-Tab]2+ dications. Intermolecular hydrogen bonding interactions between the protons of methyl groups from the Tab-Tab dications and the chlorides result in the formation ofa 2D hydrogen-bonded network. |
