| 1，4二环己基取代六元瓜环与Na(Ⅰ)自组装实体的合成与晶体结构 |
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| 引用本文： | 郑利梅,祝黔江,朱建男,张云黔,陶朱,薛赛凤,魏赞斌,龙腊生.1，4二环己基取代六元瓜环与Na(Ⅰ)自组装实体的合成与晶体结构[J].无机化学学报,2005,21(10):1583-1588. |
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| 作者姓名： | 郑利梅 祝黔江 朱建男 张云黔 陶朱 薛赛凤 魏赞斌 龙腊生 |
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| 作者单位： | 1. 贵州大学应用化学研究所,贵阳,550025
2. 厦门大学化学系,厦门,361005 |
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| 基金项目： | 国家自然科学基金资助项目(No.20362003)，科技部国际科技合作重点项目计划(No.2003DF000030)，贵州省省长资金项目，贵州省国际科技合作重点项目计划(No.2005400101) |
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| 摘 要： | A novel complex of a new 1,4-dicyclohexyl cucurbituril(DCYQ6]) with sodium(Ⅰ) ion was synthesized, and the crystal structure was determined by X-ray diffraction technique. In this self-assembled entity both the cavity interaction of DCYQ6] included a nitrate anion and the portal interaction of the dipole carbonyls of DCYQ6] with sodium cations lead to form self assembled molecular capsules. The crystal structure of the entity shows a packing of the self assembled molecular capsules connected by hydrogen bonds of water molecules. CCDC: 271400.
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| 关 键 词： | 1，4-二环己基取代六元瓜环 晶体结构 自组装实体 |
| 文章编号： | 1001-4861(2005)10-1583-06 |
| 收稿时间： | 2004-10-25 |
| 修稿时间： | 8/4/2005 12:00:00 AM |
Synthesis and Crystal Structure of a Novel Self-assembled (1,4-discyclohexyl cucurbituril) Sodium(Ⅰ) Complex |
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| ZHENG Li-Mei,ZHU Qian-Jiang,ZHU Jian-Nan,ZHANG Yun-Qian,TAO Zhu,XUE Sai-Feng,WEI Zhan-Bing and LONG La-Sheng.Synthesis and Crystal Structure of a Novel Self-assembled (1,4-discyclohexyl cucurbituril) Sodium(Ⅰ) Complex[J].Chinese Journal of Inorganic Chemistry,2005,21(10):1583-1588. |
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| Authors: | ZHENG Li-Mei ZHU Qian-Jiang ZHU Jian-Nan ZHANG Yun-Qian TAO Zhu XUE Sai-Feng WEI Zhan-Bing and LONG La-Sheng |
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| Institution: | Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Department of Chemistry, Xiamen University, Xiamen 361005 and Department of Chemistry, Xiamen University, Xiamen 361005 |
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| Abstract: | A novel complex of a new 1,4-dicyclohexyl cucurbituril(DCYQ6) with sodium(I) ion was synthesized, and the crystal structure was determined by X-ray diffraction technique. In this self-assembled entity both the cavity interaction of DCYQ6 included a nitrate anion and the portal interaction of the dipole carbonyls of DCYQ6 with sodium cations lead to form self assembled molecular capsules. The crystal structure of the entity shows a packing of the self assembled molecular capsules connected by hydrogen bonds of water molecules. CCDC: 271400. |
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| Keywords: | 1 4-dicyclohexyl cucurbituril crystal structure self-assembled entity |
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