Reductive transformation of isoprenoid cyclosulfonates into linear homoallylic alcohols and amines |
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Authors: | A. M. Moiseenkov A. N. Rechinskii E. V. Polunin O. N. Yudina I. M. Zaks |
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Affiliation: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions Isoprene, myrcene, and ocimene sultones were converted into the corresponding linear homoallylic alcohols and amines via the stage of desulfonylation of the in situ generated allylsulfinic acids. A new synthesis of myrcenol and isogeraniol has been carried out.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1820–1823, August, 1985. |
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