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Coordination chemistry of the hexavacant tungstophosphate [H2P(2W12O48]12-: synthesis and characterization of iron(III) complexes derived from the unprecedented {P2W14O54} fragment
Authors:Godin Béatrice  Vaissermann Jacqueline  Herson Patrick  Ruhlmann Laurent  Verdaguer Michel  Gouzerh Pierre
Affiliation:Laboratoire de Chimie Inorganique et Matériaux Moléculaires, UMR CNRS 7071, Institut de Chimie Moléculaire FR 2769, Université Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris Cedex 05, France.
Abstract:Clusters which display the rare cubic Fe8 topology have been obtained by reaction of the metastable hexavacant polyoxotungstate [H2P2W12O48]12- with basic trinuclear metal acetates.
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