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A total synthesis of guanacastepene C
Authors:Mehta Goverdhan  Pallavi Kotapalli  Umarye Jayant D
Affiliation:Department of Organic Chemistry, Indian Institute of Science, Bangalore, India. gm@orgchem.iisc.ernet.in
Abstract:A total synthesis of the structure corresponding to the novel tricyclic diterpene guanacastepene C has been realized in which a Knoevenagel cyclization serves as a key step to annulate the six-membered C-ring on a stereochemically secured bicyclic hydroazulene precursor.
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