Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex |
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Authors: | Huffman Lauren M Stahl Shannon S |
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Affiliation: | University of Wisconsin-Madison, Department of Chemistry, 1101 University Avenue, Madison, WI, USA. |
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Abstract: | A net trans C-N reductive elimination reaction is observed from a macrocyclic aryl-Cu(III) complex, and a mechanistic study of this reaction indicates that coordinating ligands play a role in mediating this unusual transformation. |
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