Path of “dry” electrons before localization in liquid hydrocarbons |
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Authors: | L. V. Lukin A. V. Tolmachev B. S. Yakovlev |
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Affiliation: | (1) Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka |
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Abstract: | Conclusions On the basis of measurements of values of![mgr](/content/qv45u03230207625/xxlarge956.gif) ![prime](/content/qv45u03230207625/xxlarge8242.gif) ![tau](/content/qv45u03230207625/xxlarge964.gif) in liquid hydrocarbons, it has been shown that the path length before localization of a photoliberated electron increases with increasing mobility of the excess electron, from approximately 40 Å (methylcyclohexane) to 200 Å (isooctane). In a liquid with 10–2 cm2/V·sec (methylcyclohexane, hexane), the localization takes place before or immediately after thermalization of the electron. In a liquid with >10–1 cm2/V·sec, the electron passes through the main part of its path before localization, being in thermal equilibrium with the medium.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2198–2203, October, 1985. |
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