Chiral imines and amines based on 2-hydroxypinan-3-one |
| |
| Authors: | Ya A Gur’eva O A Zalevskaya L L Frolova I N Alekseev A V Kuchin |
| |
| Institution: | (1) Institute of Chemistry, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, 167982 Syktyvkar, Russia;(2) Syktyvkar State University, 167023 Syktyvkar, Ul. Petrozavodskaya, 120, Russia |
| |
| Abstract: | The new chiral derivatives of benzylamine and 2α-hydroxypinan-3-one (1R,2R,5R)-3-(1S)-α-methylbenzylamino]-2,6,6-trimethylbicyclo3.1.1]heptan-2-ol (2), (1S,2S,3S,5S)-3-(benzylamino)-2,6,6-trimethylbicyclo3.1.1]heptan-2-ol (3), and (1R,2R,3R,5R)-3-(1S)-α-methylbenzylamino]-2,6,6-trimethylbicyclo3.1.1]heptan-2-ol (4) were synthesized and characterized. It was shown that reduction
of the benzylimines by sodium triacetoxyborohydride formed stereoselectively 3β-substituted pinanamines. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
