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Hemocompatibility and ultrafiltration performance of PAN membranes surface‐modified by hyperbranched polyesters
Authors:Xiuzhen Wei  Yaowei Fei  Yingying Shi  Jinyuan Chen  Bosheng Lv  Yongsheng Chen  Hai Xiang
Institution:1. College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou, China;2. School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA, USA;3. College of Bioengineering, Zhejiang Chinese Medical University, Hangzhou, China
Abstract:Maleic anhydride was grafted onto a polyacrylonitrile (PAN) membrane surface via ultraviolet irradiation. Then, hyperbranched polyester, with varying numbers of hydroxyl end‐groups (H20, H30, and H40), was grafted onto the PAN membrane surface by the reaction of hydroxyl groups with anhydride groups of maleic anhydride. The modified membranes were characterized by scanning electron microscopy, static water contact angle, and attenuated total reflectance‐Fourier transform infrared spectroscopy measurements. The modified membranes showed a higher water flux and better antifouling properties than pristine PAN membranes, and their hydrophilicity was significantly improved. Membrane biocompatibility was characterized by platelet adhesion, and the results indicate that the modified membranes exhibited good biocompatibility. Copyright © 2016 John Wiley & Sons, Ltd.
Keywords:hyperbranched polyester  maleic anhydride  surface modification  PAN ultrafiltration membranes
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