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Crystal and Molecular Structure of Di-chloro-bis(р-methylphenylbutylsulfide) Palladium(Ⅱ)
引用本文:Guo Song-Shan, Cui Li, Wang Hang-Zhang, Qian Pu(Department of Chemistry,University of Suzhou,Suzhou 215006)Yu Kai-Bei(Chengdu Center of Analysis and Determination,Academic Sinica,Chengdu,610041). Crystal and Molecular Structure of Di-chloro-bis(р-methylphenylbutylsulfide) Palladium(Ⅱ)[J]. 结构化学, 1994, 0(1)
作者姓名:Guo Song-Shan   Cui Li   Wang Hang-Zhang   Qian Pu(Department of Chemistry  University of Suzhou  Suzhou 215006)Yu Kai-Bei(Chengdu Center of Analysis and Determination  Academic Sinica  Chengdu  610041)
作者单位:Guo Song-Shan; Cui Li; Wang Hang-Zhang; Qian Pu(Department of Chemistry,University of Suzhou,Suzhou 215006)Yu Kai-Bei(Chengdu Center of Analysis and Determination,Academic Sinica,Chengdu,610041)
摘    要:CrystalandMolecularStructureofDi-chloro-bis(р-methylphenylbutylsulfide)Palladium(Ⅱ)¥GuoSong-Shan;CuiLi;WangHang-Zhang;QianPu(...


Crystal and Molecular Structure of Di-chloro-bis(р-methylphenylbutylsulfide) Palladium (Ⅱ)
Guo Song-Shan, Cui Li, Wang Hang-Zhang, Qian Pu. Crystal and Molecular Structure of Di-chloro-bis(р-methylphenylbutylsulfide) Palladium (Ⅱ)[J]. Chinese Journal of Structural Chemistry, 1994, 0(1)
Authors:Guo Song-Shan   Cui Li   Wang Hang-Zhang   Qian Pu
Abstract:Pd (p-CH3C6H4SC4H9)2Cl2C(22)H(32)CL2S2Pd , MR= 537. 92, space group P21/c, a=10. 336(2) , b=8. 657(1) ,c=14. 452(2) A, β=105. 19(1)°, V = 1247. 9(3) A3, Z=2 , Dc= 1. 43 g/cm ̄(-3), MoKα radiation,μ=11. 16 cm-1,F(000) = 552 , R= 0. 030 for 2417 reflections with I>3a(Ⅰ) .Pd (Ⅱ) is coordinated by two chloride atoms and two sulfur atoms of organic ligands, forming a transsquare planar with Pd-S of 2. 316(1) and Pd-Cl of 2. 303(1) A.
Keywords:crystal structure   palladium complex   chloro-methylphenylbutyl-sulfide-palladium
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