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Immobilized Osmium Clusters in the Processes of Liquid-Phase Oxidation of Cycloxehene |
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| Authors: | Kholuiskaya S. N. Pomogailo A. D. Bravaya N. M. Pomogailo S. I. Maksakov V. A. |
| Affiliation: | (1) Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia;(2) Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia;(3) Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia |
| Abstract: | The reaction of catalytic hydroxylation of olefins by organic hydroperoxides in the presence of osmium carbonyl clusters supported on polymer matrices is studied. The process occurs with the predominant formation of unsaturated alcohols. The oxidative coupling of olefins with the formation of nonconjugated dienes and in which the double bonds remain intact occurs in parallel. In the course of the reaction, changes in the chemical structures of the initial osmium clusters are not observed. |
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