Fluorine-containing allenes. Communication 7. Two directions for dehydrofluorination of 1-fluoro-1-(α-hydrohexafluoroisopropyl)ethylenes |
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Authors: | L A Rozov Yu V Zeifman N P Gambaryan Yu A Cheburkov I L Knunyants |
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Institution: | 1. Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow
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Abstract: | 1. |
Depending on the nature of the substituent in the 2 position, l-fluoro-l-(-hydrohexafluoroisopropyl)ethylenes are dehydrofluorinated to either allenes or 1,3-dienes.
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It was shown that allylic substitution is possible in the reactions of perfluoroisobutylene with carbanions; the mutual transformations of the allyl and vinyl isomers were studied.
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The perfluoroalkenylation product was obtained when perfluoroisobutylene is reacted with ketene acetal.
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