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Fluorine-containing allenes. Communication 7. Two directions for dehydrofluorination of 1-fluoro-1-(α-hydrohexafluoroisopropyl)ethylenes
Authors:L A Rozov  Yu V Zeifman  N P Gambaryan  Yu A Cheburkov  I L Knunyants
Institution:1. Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow
Abstract:
1.  Depending on the nature of the substituent in the 2 position, l-fluoro-l-(agr-hydrohexafluoroisopropyl)ethylenes are dehydrofluorinated to either allenes or 1,3-dienes.
2.  It was shown that allylic substitution is possible in the reactions of perfluoroisobutylene with carbanions; the mutual transformations of the allyl and vinyl isomers were studied.
3.  The perfluoroalkenylation product was obtained when perfluoroisobutylene is reacted with ketene acetal.
Keywords:
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